Standoffs, spacers, shims and washers from a plain-English description, with the stack height, the outside profile and the bore measured before you print.
An M3 standoff 15mm tall, hex outside 5.5mm across flats, through hole for an M3 bolt.
A round spacer 8mm outside diameter, 4.2mm bore, 6.5mm long, for an M4 bolt.
A shim 20 x 20 x 1.2mm with a 5.5mm hole in the middle and two 3.2mm holes 14mm apart.
A standoff is the simplest part on this site and the one with the least room in it. The height is the specification, the bore is fixed by the bolt, and everything that is left over is wall — usually about a millimetre of it.
A hexagon has two widths. Across the flats is what a spanner reads and what a catalogue lists; across the corners is 15.5% larger, and it is what a bounding box reads, because a bounding box does not know what a hexagon is. A 5.5 mm hex standoff measures 6.35 mm corner to corner, and a report that says 5.5 expected against 6.35 measured is describing one hexagon, not a part that came out too big. Say "5.5 mm across flats" in the prompt and the ambiguity never arises.
"M3" is the bolt. The hole the bolt goes through is 3.2 mm close or 3.4 mm normal clearance, and a hole actually printed at 3.0 mm is a hole you will be drilling out. If you want the bolt to thread into the part, say so — and expect it to be a worse idea than it sounds in plastic at this scale, where a printed thread strips long before the bolt does.
Between a Ø3.4 bore and a 5.5 mm hex there is 1.05 mm of material at the flats, and that is not a choice anyone made — it is subtraction. It is also near the floor of what prints as a solid wall rather than two skins with a gap down the middle. If the stack is carrying any load, print this family with enough perimeters to fill the wall, in something stiff, or buy the brass one.
The bounding box, the bore diameter and count, the volume, and the thinnest span the print-readiness sampler can find. What is not measured is whether the standoff will take the torque you put through the bolt: a dimensionally perfect standoff in soft plastic still crushes.